Flow induced crystallization
WebMar 30, 2024 · Understanding polymer crystallization with the presence of flow, or namely flow-induced crystallization (FIC), is crucial to optimize polymer processing … WebBased on classical nucleation theory, the current entropic reduction model (ERM) of flow-induced crystallization (FIC) treats external work as perturbation on the framework of equilibrium thermodynamics, which, however, obscures the nonequilibrium nature of FIC. In this work, in situ investigation on FIC under strong flow by combining a unique …
Flow induced crystallization
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WebFlow-induced nucleation and crystallization are observed in conjugated small molecules and polymers, and are closely related to the flow-induced polymer conformational changes and enhanced mass and heat transfer observed during crystallization. WebOct 28, 2006 · We present a study on flow-induced crystallization of polymers filled with rigid particles. The numerical simulations reveal the interplay between filler particles, the …
WebNov 7, 2009 · The transitions between the different flow regimes and the associated physical processes governing the flow-induced crystallization (FIC) processes are defined by the critical values of the Deborah numbers (De) related to the molecular orientation (De rep) and molecular stretch (De s). An extensive evaluation of experiments reported in the ... WebJul 6, 2024 · Flow-induced crystallisation of polymers from aqueous solution Introduction. In the natural world numerous strategies for efficient processing of materials have evolved 1, 2, and one... Results. PEO is crystallisable and water soluble, due to the similarity of its … We would like to show you a description here but the site won’t allow us.
WebSep 9, 2016 · Flow-induced crystallization (FIC) is a non-equilibrium thermodynamic phase transition occurring in daily industrial processing of semicrystalline polymers with an annual consumption of hundred ... WebThe nonlinear dynamics in film blowing process is simulated employing the governing equations of the system that include the flow-induced crystallization (FIC), i.e., the continuity, the two force balances (axial and circumferential), the energy, the crystallinity, and the constitutive equations of Phan-Thien Tanner (PTT) model.
WebAug 3, 2024 · We propose a unified thermodynamic model of flow-induced crystallization of polymer (uFIC), which incorporates not only the conformational entropy reduction but …
WebFeb 18, 2024 · The effects induced by the flow on polymer crystallization behavior can be summarized into three aspects, namely accelerated nucleation rate, modified crystal morphology, and newly formed crystal structure, which are all directly relevant to the end-use properties [11, 19].To attain the ultimate goal of predicting the polymer … china online advertising marketWebApr 9, 2024 · At high flow strength, a flow-induced crystallization (FIC) occurred, producing a semicrystalline material possessing a high degree of crystallinity and primarily a monoclinic lattice structure. This FIC phase formed at a temperature (450 K) high above the quiescent melting point (≈400 K) and remained stable after cessation of flow for ... china onion drying machineWebJan 19, 2024 · In this work, the flow-induced crystallization of two polylactides (PLAs) with different microstructures (different l-lactic acid contents) is studied using simple shear, … china online communityWebSep 3, 2024 · The temperature-induced crystallization-driven self-assembly (TI-CDSA) protocol allowed some control over the shape and size of some of the morphologies. ... The system used two PL1113-6300 ResiPore 3 µm 300 × 7.5 mm columns with DMF as the eluent with a flow rate of 1 mL/min and toluene as flow rate marker. The detector suite … china online businessWebJul 29, 2024 · Abstract. Flow-induced crystallization has been widely studied for a variety of polymers with the main focus on polyolefins. In this work, research has been conducted on the flow-induced ... china online buying sitesWebNov 22, 2013 · The so-called “short-term flow” protocol is widely applied in experimental flow-induced crystallization studies on polymers in order to separate the nucleation and subsequent growth processes [Liedauer et al. Int. Polym. Proc. 1993, 8, 236–244]. The basis of this protocol is the assumption that structure development during flow can be … china online brokersWebJan 1, 2024 · When polymer crystallization is induced by flow elongation, the semicrystalline morphology is affected by the orientation. The most obvious effects induced during flow are ascribed to kinetic and morphologic aspects, where in comparison with quiescent conditions the developed crystals trend to evolve from spherical to elongated … gral web ebanx comp